RTV = Room Temperature Vulcanizing. Not all RTV silicones are the same. The 2-part stuff from LureCraft or M-F or Barlows is pretty good but expensive, yet sets overnight. 1-part high-temp RTV can be had in tubes like caulk/grease but takes a LOT longer to set.
If I buy any RTV again, it'll be from Hobby Silicone.
Some guys make molds from PoP, but I like the extra Hardness and Durability of Durhams Rock Hard Water Putty. I seal mine with Clear Engine Spray Paint. Durhams is killer and cheap...it's just hard, not flexible like silicone.