There are a number of threads on thermometers and why you should NOT use an IR thermometer. There is no way you are going to get a good reading using an IR...not the least being they measure only surface temperature (and the center of the liquid is MUCH hotter) and IR thermometers are for measure temperature on a solid...NOT a liquid and the "temperature" will vary based upon the color of the material, it's composition (metal and wood will read differently) and a host of other factors.
I would not surprise me in the least that your IR thermometer would read 320 (surface temp) while the center is burning at 375+ on a good digital thermometer.
At work, we only use IR thermometers to measure the temperature of equipment...and they are calibrated using a digital thermometer. Any liquid is measured with a digital probe thermometer. As I've mentioned before, my Daughter is a Microbiologist and she can ONLY use digital thermometers are work. In a couple of my posts I've mentioned the one she uses...that you can but from Amazon for under $20 !
Here's the link:
http://www.caneycreekmolds.net/index.php?topic=1182.msg7170#msg7170Put digital thermometer into the search box (just below the CCM logo on the top right) and there are a bunch of threads that talk about plastic burning, digital thermometers, plastic continuing to cook for up to 1 minute after it comes out of the microwave etc.